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The comparison of activation parameters for reactions in different solvents requires consideration of solvation differences of both the reactants and the transition states. The comparison can be done by using potential energy diagrams, such as that illustrated below for two different solvents A and B. It is possible to measure ΔHtransfer values, which correspond to the enthalpy change associated with transfer of a solute from one solvent to another. -TS in A -TS in B ΔHtransfer data for n-hexy

4.6: Activation Energy and Rate